Absorption (physical)
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A physical or chemical phenomenon or a process in which atoms, molecules, or ions enter some bulk phase - gas, liquid or solid material. This is a different from Adsorption, since the molecules are taken up by the volume, not by surface.
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Amphiphiles
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A chemical compound possessing both hydrophilic and hydrophobic properties. Common amphiphilic substances are soap and detergent.
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Bingham Plastic
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A viscoplastic material that behaves as a rigid body at low stresses but flows as a viscous fluid at high stress. A common example is toothpaste, which will not be extruded until a certain pressure is applied to the tube. It then is pushed out as a solid plug.
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Coffee Ring Effect
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A pattern left by a puddle of particle-laden liquid after it evaporates. Named after the characteristic ring-like deposit along the perimeter of a spill of coffee. The pattern is due to capillary flow induced by the differential evaporation rates across the drop: liquid evaporating from the edge is replenished by liquid from the interior. The resulting edgeward flow can carry nearly all the dispersed material to the edge.
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Cohesion
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The action or property of like molecules sticking together, being mutually attractive. This is an intrinsic property of a substance that is caused by the shape and structure of its molecules which makes the distribution of orbiting electrons irregular when molecules get close to one another, creating electrical attraction that can maintain a macroscopic structure such as a water drop.
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Colloid
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A type of chemical mixture where one substance is dispersed evenly throughout another. The particles of the dispersed substance are only suspended in the mixture, unlike a solution, where they are completely dissolved within. This occurs because the particles in a colloid are larger than in a solution - small enough to be dispersed evenly and maintain a homogenous appearance, but large enough to scatter light and not dissolve.
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Crystallisation
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The (natural or artificial) process of formation of solid crystals precipitating from a identical solution or melt, or more rarely deposited directly from a gas. Crystallisation is also a chemical solid-liquid separation technique, in which mass transfer of a solute from the liquid solution to a pure solid crystalline phase occurs.
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Deposition (physical)
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A process in which gas transforms into solid (also known as desublimation). The reverse of deposition is sublimation. One example of deposition is the process by which, in sub-freezing air, water vapour changes directly to ice without first becoming a liquid. This is how snow forms in clouds, as well as frost and hoar frost on the ground.
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Electret
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An Electret is a dielectric material that has a quasi-permanent electric charge or dipole polarisation. An electret generates internal and external electric fields, and is the electrostatic equivalent of a permanent magnet.
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Solid particles can be attracted by the charge of an electret.
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Electrodeposition
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The process of using electrical current to reduce cations of a desired material from a solution and coat a conductive object with a thin layer of the material, such as a metal. Primarily used for depositing a layer of material to bestow a desired property (e.g., abrasion and wear resistance, corrosion protection, lubricity, aesthetic qualities, etc.) to a surface that otherwise lacks that property. Another application uses electroplating to build up thickness on undersized parts.
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Electrolysis
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A method of separating chemically bonded elements and compounds by passing an electric current through them. Electrolysis involves the passage of an electric current through an ionic substance that is either molten or dissolved in a suitable solvent, resulting in chemical reactions at the electrodes.
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Through electrolytic deposition at electrodes.
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Electrostatics
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The phenomena arising from stationary or slowly moving electric charges
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Evaporation
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The change of the physical state of aggregation (or simply state) of matter from liquid phase to gaseous phase.
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For example, evaporation is a common method of thin film deposition. The source material is evaporated in a vacuum. The vacuum allows vapour particles to travel directly to the target object (substrate), where they condense back to a solid state.
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Faraday Wave
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(or Faraday Ripples) Nonlinear standing waves that appear on liquids enclosed by a vibrating receptacle. When the vibration frequency exceeds a critical value, the flat hydrostatic surface becomes unstable. The waves can take the form of stripes, close-packed hexagons, or even squares or quasiperiodic patterns.
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Faraday waves are used as a liquid-based template for directed assembly of microscale materials including soft matter, rigid bodies and biological entities.
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Fermentation
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In an industrial context, fermentation refers to the breakdown of organic substances and re-assembly into other substances. Somewhat paradoxically, fermenter culture in industrial capacity often refers to highly oxygenated and aerobic growth conditions, whereas fermentation in the biochemical context is a strictly anaerobic process.
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Ferromagnetism
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The mechanism by which certain materials (such as iron) form permanent magnets and/or exhibit strong interactions with magnets. Responsible for commonly observed magnetism phenomena, e.g. 'fridge magnets. A material is 'ferromagnetic' only if all its magnetic ions add a positive contribution to the net magnetisation. If some of them subtract from the net magnetisation (i.e. are partially anti-aligned), then the material is 'ferrimagnetic'.
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Flocculation
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A process of contact and adhesion whereby the particles of a dispersion form larger-size clusters.
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Fluidisation
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A process similar to liquefaction whereby a granular material is converted from a static solid-like state to a dynamic fluid-like state. This process occurs when a fluid (liquid or gas) is passed up through the granular material. When fluidized, a bed of solid particles will behave as a fluid, like a liquid or gas.
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Fluidisation allows granular solid material to be manipulated as if it were a liquid, allowing liquid processing methods to be used, such as pumping.
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Gel
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A gel is a solid, jelly-like material that can have properties ranging from soft and weak to hard and tough. Gels are defined as a substantially dilute crosslinked system, which exhibits no flow when in the steady-state. By weight, gels are mostly liquid, yet they behave like solids due to a three-dimensional crosslinked network within the liquid. It is the crosslinks within the fluid that give a gel its structure (hardness) and contribute to stickiness (tack).
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Gravitation
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A natural phenomenon by which objects with mass attract one another. In everyday life, gravitation is most commonly thought of as the agency which lends weight to objects with mass.
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Lotus Leaf Effect
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The leaves of the sacred lotus flower (Nelumbo) are characterized by a very high water repellency (superhydrophobicity). Dirt particles are picked up by water droplets due to a complex micro- and nanoscopic architecture of the surface which enables minimisation of adhesion.
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Particles of dirt on a surface can be accumulated on the surface of water droplets running over the surface.
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Magnetic Field
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A vector field which surrounds magnets and electric currents, and is detected by the force it exerts on moving electric charges and on magnetic materials. When placed in a magnetic field, magnetic dipoles tend to align their axes parallel to the magnetic field. Magnetic fields also have their own energy with an energy density proportional to the square of the field intensity.
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Magnetism
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One of the phenomena by which materials exert attractive or repulsive forces on other materials. Some well-known materials that exhibit easily detectable magnetic properties (called magnets) are nickel, iron, cobalt, and their alloys; however, all materials are influenced to greater or lesser degree by the presence of a magnetic field.
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Metastability
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A general scientific concept which describes states of delicate equilibrium. A system is in a metastable state when it is in equilibrium (not changing with time) but is susceptible to fall into lower-energy states with only slight interaction. It is analogous to being at the bottom of a small valley when there is a deeper valley close by
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Nucleation
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The extremely localised budding of a distinct thermodynamic phase. Some examples of phases that may form via nucleation in liquids are gaseous bubbles, crystals or glassy regions. Creation of liquid droplets in saturated vapor is also characterized by nucleation. Most nucleation processes are physical, rather than chemical, but a few exceptions do exist (e.g. electrochemical nucleation).
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Ostwald Ripening
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An observed phenomenon in solid solutions or liquid sols that describes the change of an inhomogeneous structure over time, i.e., small crystals or sol particles dissolve, and redeposit onto larger crystals or sol particles. Occurs because larger particles are more energetically favored than smaller particles. This stems from the fact that molecules on the surface of a particle are energetically less stable than the ones in the interior. Ostwald ripening is also observed in liquid-liquid systems, causing diffusion of monomers (i.e. individual molecules or atoms) from smaller droplets to larger droplets due to greater solubility of the single monomer molecules in the larger monomer droplets.
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Example: the re-crystallization of water within ice cream which gives old ice cream a gritty, crunchy texture. Larger ice crystals grow at the expense of smaller ones within the ice cream, creating a coarser texture.
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Phase Change
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The transformation of a thermodynamic system from one phase to another. Most commonly used to describe transitions between solid, liquid and gaseous states of matter, in rare cases including plasma.
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Photophoresis
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The phenomenon that small particles suspended in gas (aerosols) or liquids (hydrocolloids) starts to migrate when illuminated by a sufficiently intense beam of light. The existence of this phenomenon is owed to a non-uniform distribution of temperature of an illuminated particle in a fluid medium.
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Physisorption
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(or physical adsorption) A type of adsorption in which the adsorbate adheres to the surface only through Van der Waals (weak intermolecular) interactions, which are also responsible for the non-ideal behaviour of real gases.
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Porosity
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The quality of being porous - i.e. having voids or spaces within a solid substance within or through which fluids can be present.
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Potential Well
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The region surrounding a local minimum of potential energy. Energy held in a potential well is unable to convert to another type of energy (kinetic energy in the case of a gravitational potential well) because it is captured in the local minimum of a potential well and so may not proceed to the global minimum of potential energy, as it would naturally tend to due to entropy.
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Sedimentation
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The motion of molecules in solutions or particles in suspensions in response to an external force such as gravity, centrifugal acceleration or electromagnetism. Sedimentation may pertain to objects of various sizes, ranging from suspensions of dust and pollen particles to cellular suspensions to solutions of single molecules such as proteins and peptides.
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Settling
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The process by which particulates settle to the bottom of a liquid and form a sediment. Particles that experience a force, either due to gravity or due to centrifugal motion will tend to move in a uniform manner in the direction exerted by that force. For gravity settling, this means that the particles will tend to fall to the bottom of the vessel, forming a slurry at the vessel base.
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Solvation
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(commonly called dissolution) The process of attraction and association of molecules of a solvent with molecules or ions of a solute. As ions dissolve in a solvent they spread out and become surrounded by solvent molecules. The bigger the ion, the more solvent molecules are able to surround it and the more it becomes solvated.
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Supercritical Fluid
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Any substance at a temperature and pressure above its critical point. It can diffuse through solids like a gas, and dissolve materials like a liquid. Additionally, close to the critical point, small changes in pressure or temperature result in large changes in density, allowing many properties to be 'tuned'.
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Supercritical fluids can be used to deposit functional nanostructured films and nanometer-size particles of metals onto surfaces. The gas-like surface tension, diffusivities, and viscosities allows access to nano pores much smaller than can be accessed by liquids The liquid-like solubilities allow much higher precursor concentrations than are typical in chemical vapour deposition.
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Supersaturation
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A solution that contains more of the dissolved material than could be dissolved by the solvent under normal circumstances. It can also refer to a vapour of a compound that has a higher (partial) pressure than the vapour pressure of that compound.
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Suspension
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A heterogeneous fluid containing solid particles that are sufficiently large for sedimentation. Usually they must be larger than 1 micrometer. The internal phase (solid) is dispersed throughout the external phase (fluid - which may be liquid or gas) through mechanical agitation, with the use of certain excipients or suspending agents.
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Thermophoresis
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(also called thermodiffusion or Soret Effect) The effect of temperature gradient on multicomponent (or isotopic) mixtures of particles (i.e. particle movement from hotter to colder regions or vice versa). Regarded as 'positive' when molecules move from hot to cold and 'negative' when the reverse is true. Typically the heavier/larger species in a mixture exhibits positive behavior while the lighter/smaller species exhibit negative.
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A thermal precipitator is an instrument that collects aerosol particles using thermophoresis to deposit the particles onto a surface. It employs a heated element, such as a wire, and a collection surface. Aerosol passing between the heated element and the cooler surface will be driven to deposit on the surface.
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Triboelectric Effect
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A type of contact electrification in which certain materials become electrically charged after they come into contact with another different material and are then separated (such as through rubbing). The polarity and strength of the charges produced differ according to the materials, surface roughness, temperature, strain, and other properties.
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For example, the attraction of particles to an object carrying a staic electric charge generated by the Triboelectric Effect
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