Adsorption
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A process that occurs when a gas or liquid solute accumulates on the surface of a solid or a liquid (adsorbent), forming a film of molecules or atoms (the adsorbate). Most industrial adsorbents fall into one of three classes: 1. Oxygen-containing compounds (e.g.silica gel and zeolites 2. Carbon-based compounds (e.g. activated carbon and graphite) 3. Polymer-based compounds
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For example, activated carbon used to purify air by adsorption of gases
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Chemisorption
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A type of adsorption whereby a molecule adheres to a surface through the formation of a chemical bond, as opposed to the Van der Waals forces which cause physisorption
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Combustion
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(or burning) A complex sequence of exothermic chemical reactions between a fuel and an oxidant accompanied by the production of heat or both heat and light in the form of either a glow or flames. Direct combustion by atmospheric oxygen is a reaction mediated by radical intermediates typically produced as a result of thermal runaway, where the heat generated by combustion is necessary to maintain the high temperature necessary for radical production.
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Conduction (electrical)
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The movement of electrically charged particles through a transmission medium (electrical conductor). The movement of charge constitutes an electric current. The charge transport may result as a response to an electric field, or as a result of a concentration gradient in carrier density, that is, by diffusion .
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Deflagration
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A technical term describing subsonic combustion that usually propagates through thermal conductivity (hot burning material heats the next layer of cold material and ignites it). Most 'fire' found in daily life, from flames to explosions, is technically deflagration. Deflagration is different from detonation (which is supersonic and propagates through shock compression).
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Detonation
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Detonation involves a supersonic exothermic front accelerating through a medium that eventually drives a shock front propagating directly in front of it. Detonations are observed in both conventional solid and liquid explosives, as well as in reactive gases.
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Electric Arc
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An electrical breakdown of a gas which produces an ongoing plasma discharge, resulting from a current flowing through normally nonconductive media such as air
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Electrolysis
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A method of separating chemically bonded elements and compounds by passing an electric current through them. Electrolysis involves the passage of an electric current through an ionic substance that is either molten or dissolved in a suitable solvent, resulting in chemical reactions at the electrodes.
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For a gaseous electrolyte.
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Electrostatic Discharge
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The sudden and momentary electric current that flows between two objects at different electrical potentials
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Entropic Explosion
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An explosion in which the reactants undergo a large change in volume without releasing a large amount of heat.
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Enzyme
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Proteins that catalyze (i.e., increase the rates of) chemical reactions. Almost all chemical reactions in a biological cell need enzymes in order to occur at rates sufficient for life. Enzymes differ from most other catalysts in that they are highly specific for their substrates
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Explosion
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A sudden increase in volume and release of energy in an extreme manner, usually with the generation of high temperatures and the release of gases.
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Fermentation
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In an industrial context, fermentation refers to the breakdown of organic substances and re-assembly into other substances. Somewhat paradoxically, fermenter culture in industrial capacity often refers to highly oxygenated and aerobic growth conditions, whereas fermentation in the biochemical context is a strictly anaerobic process.
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Incandescence
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The emission of light (visible electromagnetic radiation) from a hot body due to its temperature.
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Infrared Radiation
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Infrared (IR) radiation is electromagnetic radiation whose wavelength is longer than that of visible light (400-700 nm), but shorter than that of terahertz radiation (3-300 µm) and microwaves (~30,000 µm). Infrared radiation spans roughly three orders of magnitude (750 nm and 1000 µm).
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From energy of incident infrared radiation.
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Ionisation
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The physical process of converting an atom or molecule into an ion by adding or removing charged particles such as electrons or other ions.
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Light
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Light is electromagnetic radiation of a wavelength that is visible to the human eye (in a range from about 380 or 400 nanometres to about 760 or 780 nm)
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Using a high-power light source or a target susceptible to light
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Nuclear Fission
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The splitting of the nucleus of an atom into parts (lighter nuclei) often producing free neutrons and other smaller nuclei, which may eventually produce photons (in the form of gamma rays). Fission of heavy elements is an exothermic reaction which can release large amounts of energy both as electromagnetic radiation and as kinetic energy of the fragments (heating the bulk material where fission takes place).
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Oxidation
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A chemical reaction that involves the loss of electrons or an increase in the oxidation state by a molecule, atom or ion.
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Phase Change
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The transformation of a thermodynamic system from one phase to another. Most commonly used to describe transitions between solid, liquid and gaseous states of matter, in rare cases including plasma.
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Photo-oxidation
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Oxidation facilitated radiant energy such as UV or artificial light. This process is often the most significant component of weather degradation of polymers.
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Photodissociation
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A chemical reaction in which a chemical compound is broken down by photons. Any photon with sufficient energy can affect the chemical bonds of a chemical compound. Since a photon's energy is inversely proportional to its wavelength, electromagnetic waves with the energy of visible light or higher, such as ultraviolet light, x-rays and gamma rays are usually involved in such reactions.
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Plasma
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A partially ionized gas, in which a certain proportion of electrons are free rather than being bound to an atom or molecule. The ability of the positive and negative charges to move somewhat independently makes the plasma electrically conductive so that it responds strongly to electromagnetic fields. Plasma therefore has properties quite unlike those of solids, liquids or gases and is considered to be a distinct state of matter.
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Pyrolysis
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A thermochemical decomposition of organic material at elevated temperatures in the absence of oxygen. Pyrolysis typically occurs under pressure and at operating temperatures above 430 °C (800 °F). Pyrolysis is a special case of thermolysis.
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Pyrophoricity
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A pyrophoric substance ignites spontaneously in air at or below 55 degrees centigrade. The creation of sparks from metals is based on the pyrophoricity of small metal particles. The sparking mechanism in cigarette lighters is an example. Some liquids and gases are phyrophoric.
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In the case of pyphoric gases.
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Radiation
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A process in which energetic particles or waves travel through a medium or space. There are two distinct types of radiation; ionizing and non-ionizing.
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Redox Reactions
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Redox (shorthand for oxidation-reduction) reactions describe all chemical reactions in which atoms have their oxidation number (oxidation state) changed. This can be either a simple redox process, such as the oxidation of carbon to yield carbon dioxide (CO2) or the reduction of carbon by hydrogen to yield methane (CH4), or a complex process such as the oxidation of sugar(C6H12O6) in the human body through a series of complex electron transfer processes.
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Reduction
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A chemical reaction that involves the gain of electrons or a decrease in the oxidation state by a molecule, atom or ion.
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Solvation
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(commonly called dissolution) The process of attraction and association of molecules of a solvent with molecules or ions of a solute. As ions dissolve in a solvent they spread out and become surrounded by solvent molecules. The bigger the ion, the more solvent molecules are able to surround it and the more it becomes solvated.
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Sonoluminescence
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The emission of short bursts of light from imploding bubbles in a liquid when excited by sound.
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Sorption
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The action of both absorption and adsorption taking place simultaneously, i.e. the effect of gases or liquids being incorporated into a material of a different state and adhering to the surface of another molecule. Absorption is the incorporation of a substance in one state into another of a different state (e.g., liquids absorbed by solid or gas absorbed by liquid). Adsorption is the physical adherence or bonding of ions and molecules onto the surface of another molecule.
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Thermal Radiation
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Electromagnetic radiation emitted from the surface of an object due to the object's temperature.
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Thermolysis
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(or Thermal decomposition) A chemical decomposition caused by heat. The reaction is usually endothermic as heat is required to break chemical bonds in the compound undergoing decomposition. If decomposition is sufficiently exothermic, a positive feedback loop is created producing thermal runaway and possibly an explosion.
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Vacuum
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A volume of space that is essentially empty of matter, such that its gaseous pressure is much less than atmospheric pressure. A perfect vacuum would be one with no particles in it at all, which is impossible to achieve in practice. Physicists often discuss ideal test results that would occur in a perfect vacuum, which they simply call 'vacuum' or 'free space', and use the term partial vacuum to refer to real vacuum.
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