Adiabatic Heating
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Adiabatic heating occurs when the pressure of a gas is increased from work done on it by its surroundings, e.g. a piston. Diesel engines rely on adiabatic heating during their compression stroke to elevate the temperature sufficiently to ignite the fuel.
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Avalanche Breakdown
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A phenomenon that can occur in both insulating and semiconducting materials (solids, liquids, or gases), allowing very large currents to flow within materials which are otherwise good insulators. Occurs when the electric field in the material is great enough to accelerate free electrons to the point that, when they strike atoms in the material, they can knock other electrons free: the number of free electrons is thus increased rapidly as newly generated particles become part of the process.
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Bingham Plastic
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A viscoplastic material that behaves as a rigid body at low stresses but flows as a viscous fluid at high stress. A common example is toothpaste, which will not be extruded until a certain pressure is applied to the tube. It then is pushed out as a solid plug.
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Colloid
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A type of chemical mixture where one substance is dispersed evenly throughout another. The particles of the dispersed substance are only suspended in the mixture, unlike a solution, where they are completely dissolved within. This occurs because the particles in a colloid are larger than in a solution - small enough to be dispersed evenly and maintain a homogenous appearance, but large enough to scatter light and not dissolve.
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Conduction (electrical)
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The movement of electrically charged particles through a transmission medium (electrical conductor). The movement of charge constitutes an electric current. The charge transport may result as a response to an electric field, or as a result of a concentration gradient in carrier density, that is, by diffusion .
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Through heating resulting from the flow of current.
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Conduction (thermal)
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The spontaneous transfer of thermal energy through matter, from a region of higher temperature to a region of lower temperature. Conduction acts to equalize temperature differences. It is also described as heat energy transferred from one material to another by direct contact.
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Depressurisation
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Reduction in pressure. Rapid depressurisation can be used to create pressure differences.
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Desorption
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A phenomenon whereby a substance is released from or through a surface. The process is the opposite of sorption (i.e adsorption and absorption). This occurs in a system being in the state of sorption equilibrium between bulk phase (fluid, i.e. gas or liquid solution) and an adsorbing surface (solid or boundary separating two fluids). When the concentration (or pressure) of substance in the bulk phase is lowered, some of the sorbed substance changes to the bulk state.
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Detonation
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Detonation involves a supersonic exothermic front accelerating through a medium that eventually drives a shock front propagating directly in front of it. Detonations are observed in both conventional solid and liquid explosives, as well as in reactive gases.
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Dielectric Heating
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(also known as electronic heating, RF heating, high-frequency heating) The phenomenon in which radiowave or microwave electromagnetic radiation heats a dielectric material, especially as caused by dipole rotation.
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Electric Arc
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An electrical breakdown of a gas which produces an ongoing plasma discharge, resulting from a current flowing through normally nonconductive media such as air
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Electron Impact Desorption
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Desorption arising from electron-impact induced adsorbate surface bond breaking. Molecules on surfaces may also be chemically converted to other species by electron impact
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Electrorheological Effect
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Electrorheological (ER) fluids are suspensions of extremely fine non-conducting particles (up to 50 micrometres diameter) in an electrically insulating fluid. The apparent viscosity of ER fluids changes reversibly by an order of up to 100,000 in response to an electric field. A typical ER fluid can go from the consistency of a liquid to that of a gel, and back, with response times of the order of ms. Sometimes called the Winslow Effect.
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In the sense of a large change in apparent viscosity (a loose interpretation of Phase Change).
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Exothermic Reaction
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An exothermic reaction is a chemical reaction accompanied by the release of heat. In other words, the energy needed for the reaction to occur is less than the total energy released. As a result of this, the extra energy is released, usually in the form of heat.
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Explosion
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A sudden increase in volume and release of energy in an extreme manner, usually with the generation of high temperatures and the release of gases.
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Fermentation
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In an industrial context, fermentation refers to the breakdown of organic substances and re-assembly into other substances. Somewhat paradoxically, fermenter culture in industrial capacity often refers to highly oxygenated and aerobic growth conditions, whereas fermentation in the biochemical context is a strictly anaerobic process.
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Not a phase change in the strict sense of the term, but nonetheless a way of transforming a solid into a liquid or gas.
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Fluidisation
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A process similar to liquefaction whereby a granular material is converted from a static solid-like state to a dynamic fluid-like state. This process occurs when a fluid (liquid or gas) is passed up through the granular material. When fluidized, a bed of solid particles will behave as a fluid, like a liquid or gas.
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In the sense that solid particles can be manipulated as if they were liquid (even though, strictly speaking, a phase change has not taken place)
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Freezing
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A phase change in which a liquid turns into a solid when its temperature is lowered below its freezing point. Colloquially it is applied to water, but technically it applies to any liquid. All known liquids, except liquid helium, freeze when the temperature is lowered enough.
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Gel
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A gel is a solid, jelly-like material that can have properties ranging from soft and weak to hard and tough. Gels are defined as a substantially dilute crosslinked system, which exhibits no flow when in the steady-state. By weight, gels are mostly liquid, yet they behave like solids due to a three-dimensional crosslinked network within the liquid. It is the crosslinks within the fluid that give a gel its structure (hardness) and contribute to stickiness (tack).
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In the sense that a soild component of a gel behaves somewhat like a liquid.
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Heating
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The act of increasing temperature.
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Hydrophile
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A physical property of a molecule that can transiently bond with water (H2O) through hydrogen bonding. This is thermodynamically favorable, and makes these molecules soluble not only in water, but also in other polar solvents.
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In the sense that it can transform it so as to become soluble in a liquid.
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Infrared Radiation
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Infrared (IR) radiation is electromagnetic radiation whose wavelength is longer than that of visible light (400-700 nm), but shorter than that of terahertz radiation (3-300 µm) and microwaves (~30,000 µm). Infrared radiation spans roughly three orders of magnitude (750 nm and 1000 µm).
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From energy of incident infrared radiation.
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Joule Heating
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The process by which the passage of an electric current through a conductor releases heat. Heat generated is a function of current, resistance and time. Also known as the Joule-Lenz effect, Ohmic heating or resitive heating.
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Latent Heat
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Energy released or absorbed, by a body or a thermodynamic system, during a constant-temperature process. An example is a state of matter change, meaning a phase transition, such as ice melting or water boiling.
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Nuclear Fission
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The splitting of the nucleus of an atom into parts (lighter nuclei) often producing free neutrons and other smaller nuclei, which may eventually produce photons (in the form of gamma rays). Fission of heavy elements is an exothermic reaction which can release large amounts of energy both as electromagnetic radiation and as kinetic energy of the fragments (heating the bulk material where fission takes place).
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Nuclear Fusion
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The generation of power by the fusing together of atomic nuclei to form a heavier nucleus.
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Plasma
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A partially ionized gas, in which a certain proportion of electrons are free rather than being bound to an atom or molecule. The ability of the positive and negative charges to move somewhat independently makes the plasma electrically conductive so that it responds strongly to electromagnetic fields. Plasma therefore has properties quite unlike those of solids, liquids or gases and is considered to be a distinct state of matter.
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Regelation
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The phenomenon of melting under pressure and freezing again when the pressure is reduced. Occurs only for substances, such as ice, that have the property of expanding upon freezing, for the melting points of those substances decrease with increasing external pressure.
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Sorption
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The action of both absorption and adsorption taking place simultaneously, i.e. the effect of gases or liquids being incorporated into a material of a different state and adhering to the surface of another molecule. Absorption is the incorporation of a substance in one state into another of a different state (e.g., liquids absorbed by solid or gas absorbed by liquid). Adsorption is the physical adherence or bonding of ions and molecules onto the surface of another molecule.
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Supersaturation
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A solution that contains more of the dissolved material than could be dissolved by the solvent under normal circumstances. It can also refer to a vapour of a compound that has a higher (partial) pressure than the vapour pressure of that compound.
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Suspension
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A heterogeneous fluid containing solid particles that are sufficiently large for sedimentation. Usually they must be larger than 1 micrometer. The internal phase (solid) is dispersed throughout the external phase (fluid - which may be liquid or gas) through mechanical agitation, with the use of certain excipients or suspending agents.
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In the sense that a suspension (which is partially solid) behaves in many respects as a liquid.
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Temperature Gradient
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The variation in temperature over distance.
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Thermal Radiation
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Electromagnetic radiation emitted from the surface of an object due to the object's temperature.
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Thermolysis
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(or Thermal decomposition) A chemical decomposition caused by heat. The reaction is usually endothermic as heat is required to break chemical bonds in the compound undergoing decomposition. If decomposition is sufficiently exothermic, a positive feedback loop is created producing thermal runaway and possibly an explosion.
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Viscoelasticity
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The property of exhibiting both viscous and elastic characteristics when undergoing deformation.
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